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Title:
Oxidation and Antioxidants in Organic Chemistry and Biology |
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Division: General Organic Chem / CRC Press / 英文版 |
Author/Editor: Evgeny T. Denisov , Igor B. Afanas'ev Star:  |
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ISBN: 0824753569 |
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Introduce Date: 2007年05月08日21:45 , Release Date: 2007年05月08日21:55 |
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Introducer: 明月飞光 , Rate: 3/144 |
| Format: pdf(editorial) Download |
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| Appraiser: Reuben | Grade: +5 | Reason: ( 这本书很棒 ) | |
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| Description: |
Oxidation and Antioxidants in Organic Chemistry and Biology
Evgeny T. Denisov Inst. of Problems of Chemical Physics, Chernogolovka, Russia
Igor B. Afanas'ev All-Union Vitamin Research Institute, Moscow, Russia
List Price: $199.95
Web Price: $179.96
ISBN: 9780824753566
ISBN 10: 0824753569
Publication Date: 3/29/2005
Number of Pages: 1024
Discusses mechanisms of the formation of free radicals in biological processes
Elucidates the mechanisms of processes catalyzed by prooxidant and antioxidant enzymes
Explores the role of mitochondria and microsomes in the production of free radicals
Covers non-enzymatic and enzymatic lipid oxidative processes
Contains information on oxidative destruction of proteins and DNA
Considers the role of free radicals and oxidative stress in pathological disorders
Describes major analytical methods of free radical determination under in vitro and in vivo conditions
Delineates the chemistry of organic compounds by dioxygen in the liquid and solid state as well as oxidation in biological objects
Provides a comprehensive review of modern achievements in the field of oxidation of organic compounds
Includes tables with a comprehensive collection of data on free radical generation and activity of catalysis in oxidative systems
Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information about mechanisms of action of antioxidants, their reactivity, reactions of intermediates, synergism, and antioxidants with cyclic mechanism action. Supplying useful, quantitative data in tables that make the information easy to find, the authors highlight the peculiarities of mechanisms involved in the oxidation of hydrocarbons, polymers, and different organic compounds.
The book provides tabulated values of strengths of C-H bonds of oxygen-containing compounds; of O-H bonds of hydroperoxides, alcohols, and acids; and of attacked antioxidant bonds. The authors collect and discuss over 3000 rate constants of different reactions of peroxyl radicals in oxidation and co-oxidation. They describe a new semiempiric theory of reactivity of reactants in elementary oxidative steps and the algorithm of calculation of activation energies, rate constants, and geometrical parameters of the transition states of free radical reactions. After elucidating the chemistry and kinetics of antioxidant action, the book covers oxidative processes that occur in biological systems.
Table of Contents
Preface
CHEMISTRY AND KINETICS OF ORGANIC COMPOUNDS OXIDATION BY DIOXYGEN
Molecular Products and Thermochemistry of Hydrocarbon Oxidation
Chain Mechanism of Liquid-Phase Oxidation of Hydrocarbons
Initiation of Liquid-Phase Oxidation
Oxidation as an Autoinitiated Chain Reaction
Co-Oxidation of Hydrocarbons
Reactivity of the Hydrocarbons in Reactions with Peroxyl, Alkoxyl, and Alkyl Radicals
Oxidation of Alcohols and Ethers
Oxidation of Carbonyl Compounds and Decarboxylation of Acids
Oxidation of Amines, Amides, and Esters
Catalysis in Liquid-Phase Hydrocarbon Oxidation
Sulfoxidation of Hydrocarbons
Oxidation of Polymers
CHEMISTRY OF ANTIOXIDANTS
Theory of Inhibition of Chain Oxidation of Organic Compounds
Antioxidants Reacting with Peroxyl Radicals
Cyclic Chain Termination in Oxidation of Organic Compounds
Hydroperoxide Decomposing Antioxidants
Synergism of Antioxidant Action
Peculiarities of Antioxidant Action in Polymers
Heterogeneous Inhibition of Oxidation
BIOLOGICAL OXIDATION AND ANTIOXIDANTS
Initiators of Free Radical-Mediated Processes
Generation of Free Radicals by Prooxidant Enzymes
Production of Free Radicals by Mitochondria
Production of Free Radicals by Microsomes
Nonenzymatic Lipid Peroxidation
Enzymatic Lipid Peroxidation
Oxidation of Proteins
DNA Oxidative Damage
Antioxidants
Antioxidant Enzymes
Free Radicals and Oxidative Stress in Pathophysiological Processes
Comments on Contemporary Methods of Oxygen and Nitrogen Free Radical Detection
Index
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